Characterization of the structural and magnetic properties of gd thin films

Citation
Characterization of the structural and magnetic properties of gd thin films

Material Information

Title:
Characterization of the structural and magnetic properties of gd thin films
Creator:
Williams, Daryl
Place of Publication:
[Tampa, Fla]
Publisher:
University of South Florida
Publication Date:
Language:
English

Subjects

Subjects / Keywords:
Magnetocaloric effect
Nanostructuring
Magnetic entropy
Dissertations, Academic -- Physics -- Masters -- USF ( lcsh )
Genre:
non-fiction ( marcgt )

Notes

Abstract:
ABSTRACT: The standard material by which all materials exhibiting magnetocaloric effect are measured is Gadnolinium. In this work we are attempting to understand how nanostructuring can impact the magnetocaloric effect, to this end we have grown Gd in various thin film structures. The samples made were grown via magnetron sputtering on MgO(100) substrates. Samples of thick Gd (2000 Å) were grown and sandwiched between two layers of Cr or W and annealed at increasing temperatures to study how this can perturb the magnetic and structural properties of the Gd. Another set of samples was grown in which Gd (at various thicknesses) is in a multilayer system with W. Here the purpose is to explore how changing the thickness of the Gd can change its magnetic properties. Using the appropriate Maxwell relation, the magnetic entropy change was observed to increase with increasing annealing temperature. In a 0-4T magnetic field change, the peak entropy was found to go from approximately 1.5 J/kg-K for the unannealed sample to 4.4 J/kg-K when annealed to 600°C. The multilayers were found to all have a TC near 280 K, in contrast with what is predicted by finite size scaling. This is likely due to pinholes in the W layers allowing the Gd to act as one magnetic material.
Thesis:
Thesis (MS)--University of South Florida, 2010.
Bibliography:
Includes bibliographical references.
System Details:
Mode of access: World Wide Web.
System Details:
System requirements: World Wide Web browser and PDF reader.
General Note:
Title from PDF of title page.
General Note:
Document formatted into pages; contains X pages.
Statement of Responsibility:
by Daryl Williams.

Record Information

Source Institution:
University of South Florida Library
Holding Location:
University of South Florida
Rights Management:
All applicable rights reserved by the source institution and holding location.
Resource Identifier:
E14-SFE0004667 ( USFLDC DOI )
e14.4667 ( USFLDC Handle )

Postcard Information

Format:
Book

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ABSTRACT: The standard material by which all materials exhibiting magnetocaloric effect are measured is Gadnolinium. In this work we are attempting to understand how nanostructuring can impact the magnetocaloric effect, to this end we have grown Gd in various thin film structures. The samples made were grown via magnetron sputtering on MgO(100) substrates. Samples of thick Gd (2000 ) were grown and sandwiched between two layers of Cr or W and annealed at increasing temperatures to study how this can perturb the magnetic and structural properties of the Gd. Another set of samples was grown in which Gd (at various thicknesses) is in a multilayer system with W. Here the purpose is to explore how changing the thickness of the Gd can change its magnetic properties. Using the appropriate Maxwell relation, the magnetic entropy change was observed to increase with increasing annealing temperature. In a 0-4T magnetic field change, the peak entropy was found to go from approximately 1.5 J/kg-K for the unannealed sample to 4.4 J/kg-K when annealed to 600C. The multilayers were found to all have a TC near 280 K, in contrast with what is predicted by finite size scaling. This is likely due to pinholes in the W layers allowing the Gd to act as one magnetic material.
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Magnetic entropy
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