Carbon dioxide, ground air and carbon cycling in Gibraltar karst

Citation

Material Information

Title:
Carbon dioxide, ground air and carbon cycling in Gibraltar karst
Series Title:
Geochimica et Cosmochimica Acta
Creator:
Mattey, D.P.
Atkinson, T.C.
Barker, J.A.
Fisher, R.
Latin, J.P.
Durrell, R.
Ainsworth, M
Publication Date:
Language:
English

Subjects

Subjects / Keywords:
Speleothem ( local )
Paleoclimate ( local )
Semi-Arid ( local )
Tracing ( local )
Drip Water ( local )
Evaporation ( local )
Stable Isotopes ( local )
Genre:
serial ( sobekcm )

Notes

Abstract:
We put forward a general conceptual model of CO2 behaviour in the vadose zone of karst aquifers, based on physical principles of air flow through porous media and caves, combined with a geochemical interpretation of cave monitoring data. This ‘Gibraltar model’ links fluxes of water, air and carbon through the soil with the porosity of the vadose zone, the circulation of ground air and the ventilation of caves. Gibraltar hosts many natural caves whose locations span the full length and vertical range of the Rock. We report results of an 8-year monitoring study of carbon in soil organic matter and bedrock carbonate, dissolved inorganic carbon in vadose waters, and gaseous CO2 in soil, cave and ground air. Results show that the regime of cave air CO2 results from the interaction of cave ventilation with a reservoir of CO2-enriched ground air held within the smaller voids of the bedrock. The pCO2 of ground air, and of vadose waters that have been in close contact with it, are determined by multiple factors that include recharge patterns, vegetation productivity and root respiration, and conversion of organic matter to CO2 within the soil, the epikarst and the whole vadose zone. Mathematical modelling and field observations show that ground air is subject to a density-driven circulation that reverses seasonally, as the difference between surface and underground temperatures reverses in sign. The Gibraltar model suggests that cave air pCO2 is not directly related to CO2 generated in the soil or the epikarstic zone, as is often assumed. Ground air CO2 formed by the decay of organic matter (OM) washed down into the deeper unsaturated zone is an important additional source of pCO2. In Gibraltar the addition of OM-derived CO2 is the dominant control on the pCO2 of ground air and the Ca-hardness of waters within the deep vadose zone. The seasonal regime of CO2 in cave air depends on the position of a cave in relation to the density-driven ground air circulation pattern which is itself determined by the topography, as well a
Original Version:
Geochimica et Cosmochimica Acta, Vol. 184, no. 1 (2016-07-01).

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Source Institution:
University of South Florida Library
Holding Location:
University of South Florida
Rights Management:
This object is protected by copyright, and is made available here for research and educational purposes. Permission to reuse, publish, or reproduce the object beyond the bounds of Fair Use or other exemptions to copyright law must be obtained from the copyright holder.

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University of South Florida
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